{"created":"2023-06-20T13:22:43.429876+00:00","id":3394,"links":{},"metadata":{"_buckets":{"deposit":"6674e563-d15b-44a7-be35-7d07206c140b"},"_deposit":{"created_by":21,"id":"3394","owners":[21],"pid":{"revision_id":0,"type":"depid","value":"3394"},"status":"published"},"_oai":{"id":"oai:ir.soken.ac.jp:00003394","sets":["1:283"]},"author_link":["1024","345","1023","1026","1028","1025","1029","1027","1030","346","1031","1032"],"item_10001_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1981-09-10","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"24","bibliographicPageEnd":"268","bibliographicPageStart":"261","bibliographic_titles":[{"bibliographic_title":"天然有機化合物討論会講演要旨集"}]}]},"item_10001_creator_3":{"attribute_name":"著者別名","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"TSUJIMOTO, Kazuo"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"TOKUNAGA, Fumio"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"BALOGH-NAIR, V"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"NAKANISHI, Koji"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"WATANABE, Masakatsu"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"HATTORI, Hiroyuki"}],"nameIdentifiers":[{}]}]},"item_10001_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The purpose of this study on photoreception of modified bacteriorhodopsins involves obtaining information on the structure of the protein by chemically analyzing bacteriorhodopsins which are reconstituted with artificial retinals and the opsin, and by comparison of their properties with these of the native bacteriorhodopsin. We report structural contribution of the protein to the bathochromic shifts and photochemical behavior of artificial bacteriorhodopsin. 1) Hydroretinals and hydrorhodopsins were synthesized to investigate the protein circumstances. 'Opsin shift', one of the indicator, was defined as λ_<max> of the protonated Schiff base of n-butylamine minus λ_<max> of the corresponding pigment (cm^<-1>). Point charge model was proposed that another anion except a counter ion of the Schiff base would be located not on the side chain but near the cyclohexene ring. 2) Modification of cyclohexene ring to phenyl ring strongly affected the opsin shift, while introduction of bromine atom to side chain was less effective. 3) Irradiation upon bacteriorhodopsin involving Np-retinal gave rise to anomalous photoisomerization of retinal moiety.","subitem_description_type":"Abstract"}]},"item_10001_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"天然有機化合物討論会 "}]},"item_10001_relation_12":{"attribute_name":"論文ID（NAID）","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"110006678238","subitem_relation_type_select":"NAID"}}]},"item_10001_relation_17":{"attribute_name":"関連サイト","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"CiNii 論文PDF - オープンアクセス"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://ci.nii.ac.jp/naid/110006678238","subitem_relation_type_select":"URI"}}]},"item_10001_rights_15":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 天然有機化合物討論会 "}]},"item_10001_source_id_11":{"attribute_name":"書誌レコードID (NCID)","attribute_value_mlt":[{"subitem_source_identifier":"AN00154136","subitem_source_identifier_type":"NCID"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"metadata only access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_14cb"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"辻本 , 和雄"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"徳永 , 史生"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"BALOGH-NAIR, V"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"中西 , 香爾"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"渡辺, 正勝"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"服部 , 宏之"}],"nameIdentifiers":[{}]}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"34 高度好塩菌の紫膜におけるレチナールアナログを用いる光受容","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"34 高度好塩菌の紫膜におけるレチナールアナログを用いる光受容"},{"subitem_title":"34 CHEMICAL MODIFICATION OF RETINAL MOIETY IN PURPLE MEMBRANE","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"21","path":["109","283"],"pubdate":{"attribute_name":"公開日","attribute_value":"2013-02-13"},"publish_date":"2013-02-13","publish_status":"0","recid":"3394","relation_version_is_last":true,"title":["34 高度好塩菌の紫膜におけるレチナールアナログを用いる光受容"],"weko_creator_id":"21","weko_shared_id":-1},"updated":"2023-06-20T15:27:13.500462+00:00"}