{"_buckets": {"deposit": "1ce3c26c-57a0-476d-85d0-55cf4cb07e3b"}, "_deposit": {"created_by": 21, "id": "3212", "owners": [21], "pid": {"revision_id": 0, "type": "depid", "value": "3212"}, "status": "published"}, "_oai": {"id": "oai:ir.soken.ac.jp:00003212", "sets": ["34"]}, "author_link": ["361", "360"], "item_2_creator_3": {"attribute_name": "著者名(英)", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "HIROTA, Eizi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "361", "nameIdentifierScheme": "WEKO"}]}]}, "item_2_date_4": {"attribute_name": "発行日", "attribute_value_mlt": [{"subitem_date_issued_datetime": "2012-05-28", "subitem_date_issued_type": "Created"}]}, "item_2_description_13": {"attribute_name": "研究課題番号", "attribute_value_mlt": [{"subitem_description": "２１５５０００９", "subitem_description_type": "Other"}]}, "item_2_description_14": {"attribute_name": "フォーマット", "attribute_value_mlt": [{"subitem_description": "application/pdf", "subitem_description_type": "Other"}]}, "item_2_description_16": {"attribute_name": "研究期間", "attribute_value_mlt": [{"subitem_description": "2009～2011", "subitem_description_type": "Other"}]}, "item_2_description_17": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "研究成果の概要（和文）：Stanton が理論計算から提案した振動帰属を分光実験により検討し、\r\n従来の帰属が正しいことを明らかにした。振電相互作用の重要な一因子として、不対電子と縮\r\n重振動の対称軸まわりの角運動量が強く結合していることを見出した。B–X, 0–0 バンドの一部\r\nを、遷移周波数の和・差の規則やゼーマン効果により帰属することに成功した。\r\n研究成果の概要（英文）：We have experimentally examined a theoretical proposal made by\r\nStanton on the vibrational assignment and have established the traditional assignment to\r\nbe correct. We have discovered the angular momenta along the symmetry axis, of the\r\nunpaired electron orbital and the degenerate vibrational motions to be coupled strongly,\r\nwhich is a most important vibronic coupling mechanism. We have succeeded in assigning\r\nsome part of the B–X, 0–0 band, based upon ground–state combination differences of the\r\ntransition frequencies and Zeeman effects.", "subitem_description_type": "Abstract"}]}, "item_2_description_18": {"attribute_name": "科研費研究者番号", "attribute_value_mlt": [{"subitem_description": "30011464 | http://rns.nii.ac.jp/d/nr/1000030011464", "subitem_description_type": "Other"}]}, "item_2_description_6": {"attribute_name": "内容記述", "attribute_value_mlt": [{"subitem_description": "科学研究費補助金研究成果報告書 \r\n研究代表者：廣田 榮治 ［総合研究大学院大学学融合推進センター特任研究員］ \r\n研究分担者：川口建太郎［岡山大学自然科学研究科教授］\r\n石渡孝［広島市立大学情報科学部教授］", "subitem_description_type": "Other"}]}, "item_2_relation_11": {"attribute_name": "関連サイト", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "KAKEN（科学研究費補助金データーベース）"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "http://kaken.nii.ac.jp/d/r/30011464.ja.html", "subitem_relation_type_select": "URI"}}]}, "item_2_text_19": {"attribute_name": "研究分野", "attribute_value_mlt": [{"subitem_text_value": "化学"}]}, "item_2_text_20": {"attribute_name": "研究種目", "attribute_value_mlt": [{"subitem_text_value": "基盤研究(C)"}]}, "item_2_text_21": {"attribute_name": "科研費の分科・細目", "attribute_value_mlt": [{"subitem_text_value": "基礎化学、物理化学"}]}, "item_2_text_5": {"attribute_name": "報告年度", "attribute_value_mlt": [{"subitem_text_value": "2012"}]}, "item_2_version_type_12": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "廣田, 榮治"}], "nameIdentifiers": [{"nameIdentifier": "360", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "1000030011464", "nameIdentifierScheme": "NRID", "nameIdentifierURI": " "}, {"nameIdentifier": "30011464", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://kaken.nii.ac.jp/ja/search/?qm=30011464"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2012-01-01"}], "displaytype": "simple", "download_preview_message": "", "file_order": 0, "filename": "21550009seika.pdf", "filesize": [{"value": "291.6 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_11", "mimetype": "application/pdf", "size": 291600.0, "url": {"label": "研究成果報告書", "url": "https://ir.soken.ac.jp/record/3212/files/21550009seika.pdf"}, "version_id": "6024bf9d-ac2e-4480-9c3c-7b86c3b07c8c"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "NOｘ分子、硝酸ラジカル、振電相互作用、赤外スペクトル、動的分子構造", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "jpn"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "research report", "resourceuri": "http://purl.org/coar/resource_type/c_18ws"}]}, "item_title": "基本的ＮＯｘ分子：ＮＯ３ラジカルの動的分子構造", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "基本的ＮＯｘ分子：ＮＯ３ラジカルの動的分子構造"}, {"subitem_title": "Dynamical molecular structure of the NO3 radical: a fundamental NOx molecule", "subitem_title_language": "en"}]}, "item_type_id": "2", "owner": "21", "path": ["34"], "permalink_uri": "https://ir.soken.ac.jp/records/3212", "pubdate": {"attribute_name": "公開日", "attribute_value": "2012-01-01"}, "publish_date": "2012-01-01", "publish_status": "0", "recid": "3212", "relation": {}, "relation_version_is_last": true, "title": ["基本的ＮＯｘ分子：ＮＯ３ラジカルの動的分子構造"], "weko_shared_id": -1}