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  1. 010 学術雑誌論文
  2. 渡辺, 正勝 / WATANABE, Masakatsu

Strong donation of the hydrogen bond of tyrosine during photoactivation of the BLUF domain

https://ir.soken.ac.jp/records/3877
https://ir.soken.ac.jp/records/3877
2db10033-29a6-40ef-8650-8bdf30e377a0
Item type 学術雑誌論文 / Journal Article(1)
公開日 2013-08-12
タイトル
タイトル Strong donation of the hydrogen bond of tyrosine during photoactivation of the BLUF domain
タイトル
言語 en
タイトル Strong donation of the hydrogen bond of tyrosine during photoactivation of the BLUF domain
言語
言語 eng
資源タイプ
資源タイプ識別子 http://purl.org/coar/resource_type/c_6501
資源タイプ journal article
アクセス権
アクセス権 metadata only access
アクセス権URI http://purl.org/coar/access_right/c_14cb
著者 IWATA, Tatsuya

× IWATA, Tatsuya

WEKO 1885

IWATA, Tatsuya

Search repository
WATANABE, Akihide

× WATANABE, Akihide

WEKO 1886

WATANABE, Akihide

Search repository
ISEKI, Mineo

× ISEKI, Mineo

WEKO 824

ISEKI, Mineo

Search repository
WATANABE, Masakatsu

× WATANABE, Masakatsu

WEKO 346

WATANABE, Masakatsu

Search repository
KANDORI, Hideki

× KANDORI, Hideki

WEKO 1887

KANDORI, Hideki

Search repository
著者別名 渡辺, 正勝

× 渡辺, 正勝

WEKO 345
NRID 1000040124226
e-Rad 40124226

渡辺, 正勝

Search repository
抄録
内容記述タイプ Abstract
内容記述 In the photoreaction of BLUF (sensor of blue light using FAD) domains, conserved Tyr/Gln nearby the FAD chromophore plays a crucial role in the formation of a red-shifted intermediate. The intermediate appears accompanying a hydrogen-bonding alteration of the Tyr/Gln. In order to reveal the hydrogen-bonding structure of the Tyr/Gln active center and FAD, FTIR spectroscopy was applied in the 4000-1800 cm -1 region, where X-H stretches appear. The present FTIR data show an unusually low O-H stretching vibration of tyrosine at 2800-2600 cm -1. This provides direct evidence of the light-induced switch of the hydrogen-bonding network, where the conserved Tyr (Tyr21 for AppA) donates an unusually strong hydrogen bond in the intermediate.
書誌情報 Journal of Physical Chemistry Letters
en : Journal of Physical Chemistry Letters

巻 2, 号 9, p. 1015-1019, 発行日 2011-05-05
出版者
出版者 ACP Publications
ISSN
収録物識別子タイプ ISSN
収録物識別子 19487185
DOI
識別子タイプ DOI
関連識別子 http://doi.org/10.1021/jz2003974
関連名称 10.1021/jz2003974
権利
権利情報 © 2011 American Chemical Society
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